Synthesis of cationic cobaltocenophane monomers: Isomerization and ring-opening metathesis polymerization

Alcohol-promoted ring-opening alkyne metathesis polymerization.

Alcohol is the answer! An inactive, air-stable, dimeric molybdenum alkylidyne complex is activated toward ring-opening alkyne metathesis polymerization (ROAMP) by the addition of methanol. The ROAMP is compatible with water and phenol-containing substrates and with the in situ photochemical generation of alkyne monomers from cyclopropenones.

Catalytic living ring-opening metathesis polymerization.

In living ring-opening metathesis polymerization (ROMP), a transition-metal-carbene complex polymerizes ring-strained olefins with very good control of the molecular weight of the resulting polymers. Because one molecule of the initiator is required for each polymer chain, however, this type of polymerization is expensive for widespread use. We have now designed a chain-transfer agent (CTA) cap...

Supported Catalysts Useful in Ring-Closing Metathesis, Cross Metathesis, and Ring-Opening Metathesis Polymerization

Ruthenium and molybdenum catalysts are widely used in synthesis of both small molecules and macromolecules. While major developments have led to new increasingly active catalysts that have high functional group compatibility and stereoselectivity, catalyst/product separation, catalyst recycling, and/or catalyst residue/product separation remain an issue in some applications of these catalysts. ...

Ring-Opening Metathesis Polymerization of Functionalized-Low-Strain Monomers with Ruthenium-Based Catalysts

Synthesis of hybrid block copolymers via integrated ring-opening metathesis polymerization and polymerization of NCA.

Linear hybrid block copolymers with well controlled molecular weights and narrow polydispersities were synthesized via ring-opening metathesis polymerization (ROMP) followed by ring-opening polymerization of amino acid N-carboxyanhydrides.